How does the Earth system generate and maintain thermodynamic disequilibrium and what does it imply for the future of the planet?
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3261436/
… "When we deal with the Earth system, a good choice for the boundary is the top of the atmosphere. There, the dominant exchange is radiative, with low entropy solar radiation—in terms of its photon composition as well as its confinement to a narrow solid angle—entering the Earth system and terrestrial radiation with some scattered solar radiation being returned to space. With this choice of boundary, the Earth is almost a closed system (ignoring the relatively small exchange owing to gravity and mass, such as hydrogen escape to space that could have played an important role in the Earth’s past).”…
… "To understand the drivers for present-day disequilibrium, we need to estimate the generation rates of free energy within the Earth system. These can be estimated by considering the primary drivers that supply free energy from external sources and that feed the hierarchy of transfer shown in
figure 2. Using these drivers, a global free energy budget is derived and shown in
figure 4. In contrast to the well-established global energy balance, the free energy balance emphasizes the importance of the biota in the planetary free energy generation (in particular, in the form of chemical free energy) and highlights the magnitude of human activity in dissipating free energy. The estimates are based on Kleidon [
17] and are described in the following sections.”…
… "
Solar photochemical engines. Incident solar radiation contains wavelengths that can be used to generate chemical free energy when visible or ultraviolet radiation is absorbed by electronic absorption or photodissociation. Photodissociation can, in principle, generate radicals that are associated with free energy, but it is omitted here because those compounds have very short residence times and therefore unlikely to result in sustained free energy generation of significant magnitude. Photosynthesis is able to generate longer lasting free energy using complex photochemistry that prevents rapid dissipation. Using typical values for global gross primary productivity and typical free energy content of carbohydrates yields a generation rate of chemical free energy of about 215 TW [
6].”…
… "The free energy used for human activities are, of course, drawn out of the Earth system and thereby affect its state. At present, much of the free energy needs for industrial use are met by depleting a stock of geological free energy (in the form of fossil fuels) and this results in global climatic change owing to higher concentrations of carbon dioxide in the Earth's atmosphere. If this depletion is going to be replaced by renewable sources of free energy—as commonly suggested to avoid emissions of carbon dioxide—then this is going to leave an impact on the free energy balance of the planet. Other impacts of human activity, such as the emission of methane, nitrous oxide or soot, also relate, directly or indirectly, to the combustion of fuels or to food production, and should also relate to the Earth's free energy balance. Hence, it would seem appropriate to relate human activity as well as its impacts on the Earth system to its basic driver, the need for free energy. This need for free energy would seem to be the most important metric to measure the impact of humans on the planet and would seem to serve to be a highly useful metric to evaluate potential future impacts.”…
… "I have provided a holistic description of the functioning of the whole Earth system that is grounded in the generation, transfer and dissipation of free energy from external forcings to geochemical cycling and the associated fundamental limits to these rates. Because free energy generation is needed to maintain a disequilibrium state, this description allows us to understand why the Earth system is maintained far from equilibrium without violating the second law of thermodynamics. I showed how biotic activity generates substantial amounts of chemical free energy by exploiting free energy in solar photons that is not accessible to purely physical heat engines. Hence, Lovelock's notion of chemical disequilibrium within the Earth's atmosphere as a sign for widespread life can be substantiated and quantified. This paper can hence be seen as a direct continuation of the work by Lovelock [
1,
2] on understanding the Earth as a single system that is strongly shaped by life.”…
… "The only sustainable way to meet the increasing needs for free energy by human activity would seem to use human technology in such a way that it would enhance the overall ability of the Earth system to generate free energy. This was illustrated using the two examples of ‘desert greening’ and the direct use of solar energy by photovoltaics or by heat engines using direct solar radiation in deserts. Even though this would require careful analysis and planning of potential, detrimental side effects, it would seem that it is only through the large-scale use of human technology that the Earth system could sustainably generate more free energy, yielding a more prosperous and empowered future of the planet.”…